D. Energy and Society · Thermal and Nuclear EnergyRadioactive Half-Life
D3.11 A1.6 A1.8 A1.10About 70 minutes
Learning goals- I can explain what half-life means and why radioactive decay is random for single nuclei but predictable for large numbers.
- I can calculate the amount of a radioisotope remaining after a whole number of half-lives, and use N = N₀(1/2)^(t/T).
- I can find a half-life or an age (such as a carbon-dating age) from data or a graph.
- I can describe applications and consequences of half-life in medicine, dating and nuclear waste.
Words to know
half-life (T or t½)
The time it takes for half of the radioactive nuclei in a sample to decay. Each radioisotope has its own half-life.
radioisotope
A radioactive isotope of an element, such as carbon-14 or iodine-131.
activity
The number of nuclei that decay each second in a sample. Unit: becquerel (Bq); 1 Bq = 1 decay per second.
decay curve
A graph of the amount of a radioisotope (or its activity) against time. It drops by half every half-life.
carbon dating
Estimating the age of once-living material from how much of its carbon-14 has decayed.
A hospital clock that keeps perfect time
In hospitals across Canada, patients receive tiny amounts of a radioisotope called technetium-99m so doctors can take pictures of bones, the heart or other organs with a special camera. Doctors choose it partly because of its half-life of about 6 hours. Long enough to take the pictures, short enough that a day later only a small fraction of it is left.
No one can say when any one nucleus of technetium-99m will decay. But for billions of them, the pattern is as reliable as a clock: every 6 hours, half of whatever is left decays. That reliable pattern is called half-life, and it is used everywhere from cancer treatment to dating ancient campfires.
Random for one, predictable for many
Radioactive decay is random. A single unstable nucleus might decay in the next second or in a thousand years; there is no way to know. Nothing outside the nucleus (heat, pressure, chemistry) speeds it up or slows it down.
But every nucleus of a given radioisotope has the same chance of decaying in a given time. With a huge number of nuclei, that chance turns into a predictable rule: in a fixed amount of time, the same fraction decays.
The half-life is the time it takes for half of the radioactive nuclei in a sample to decay. After one half-life, ½ remain; after two, ¼; after three, ⅛; and so on. Notice that the amount never quite reaches zero in this model; it just keeps halving.
The activity of a sample (decays per second, measured in becquerels, Bq) is proportional to the number of radioactive nuclei left, so it also halves every half-life.
A model with 64 nuclei. Which nuclei decay is random, but each half-life about half of the remaining ones decay: 64, 32, 16, 8.| Radioisotope | Half-life | Decay | Use or importance |
|---|
| technetium-99m | about 6.0 hours | γ | medical imaging |
| iodine-131 | about 8.0 days | β, γ | treating thyroid conditions |
| cobalt-60 | about 5.3 years | β, γ | cancer therapy; sterilizing medical supplies |
| tritium (hydrogen-3) | about 12.3 years | β | self-lit exit signs; fusion research |
| americium-241 | about 432 years | α | ionization smoke alarms |
| carbon-14 | about 5730 years | β | carbon dating |
| plutonium-239 | about 24 000 years | α | made in reactors; part of long-lived used fuel |
| uranium-238 | about 4.5 billion years | α | most of natural uranium; dating rocks |
Half-lives range from fractions of a second to billions of years.Calculating with half-life
If N₀ is the starting amount (number of nuclei, mass, or activity), T is the half-life and t is the time that has passed, then the amount left is:
N = N₀ (½)^(t/T)
The exponent t/T is the number of half-lives that have passed. When it is a whole number, you can just halve repeatedly. When it is not, use the y^x key on a scientific calculator. (You study exponential functions like this in MCR3U, and solving for t when it is in the exponent uses logarithms in MHF4U.)
Worked exampleExample 1: Iodine-131
A hospital receives 80 mg of iodine-131 (half-life 8.0 days). How much is left after 24 days?
- Number of half-lives: t/T = 24 ÷ 8.0 = 3.
- Halve three times: 80 → 40 → 20 → 10 mg.
- Or: N = 80(½)³ = 80 × ⅛ = 10 mg.
10 mg of iodine-131 remains (the rest has decayed into xenon-131).
A decay curve. Whatever the radioisotope, the amount halves each half-life: 100%, 50%, 25%, 12.5%, 6.25%...Worked exampleExample 2: Carbon dating
Living things keep taking in carbon, so the proportion of carbon-14 in a living tree stays about the same as in the air. When the tree dies, its carbon-14 decays and is not replaced. A piece of charcoal from an old fire pit has 25% of the carbon-14 that a living tree has. How old is it? (T = 5730 years)
- 25% = ¼ = (½)², so 2 half-lives have passed.
- Age = 2 × 5730 = 11 460 years (about 11 000 years).
The charcoal is about 11 460 years old.
Worked exampleExample 3: Not a whole number of half-lives
A cobalt-60 source (T = 5.3 years) had an activity of 4.0 × 10¹³ Bq when it was installed in a hospital. What is its activity after 8.0 years?
- Number of half-lives: t/T = 8.0 ÷ 5.3 = 1.509...
- N = N₀(½)^(t/T) = 4.0 × 10¹³ × (0.5)^1.509
- On a calculator: 0.5 ^ 1.509 = 0.351.
- Activity = 4.0 × 10¹³ × 0.351 ≈ 1.4 × 10¹³ Bq.
- Check: between 1 half-life (2.0 × 10¹³) and 2 half-lives (1.0 × 10¹³). Reasonable.
Worked exampleExample 4: Finding a half-life from data
A Geiger counter measures the activity of a sample: 800 counts per second at t = 0, 400 at t = 15 min, 200 at t = 30 min, 100 at t = 45 min. Find the half-life.
- The activity halves (800 → 400) in 15 minutes, and halves again every 15 minutes after that.
- T = 15 minutes. (In a real experiment, subtract the background count first, and read the half-life from a smooth curve of best fit because counts vary randomly.)
Applications and consequences
Medicine. Radioisotopes for imaging inside the body are chosen with short half-lives (hours to days), so the patient's dose drops quickly. Sources for radiation therapy and sterilizing equipment, like cobalt-60, have half-lives of years, so they stay useful for a long time. Canada is a major supplier of cobalt-60, which is produced in some Ontario CANDU reactors.
Dating. Carbon-14 dates once-living material up to about 50 000 years old (after that, too little carbon-14 is left to measure). Isotopes with much longer half-lives, like uranium-238, are used to date rocks billions of years old.
Smoke alarms. Americium-241's half-life of 432 years means the source in a smoke alarm hardly weakens during the alarm's life.
Nuclear waste. Used reactor fuel contains many radioisotopes. Short-lived ones become much less radioactive within years, but some, such as plutonium-239, have half-lives of thousands of years. Waste containing them must be isolated from people and the environment for a very long time. This is one of the biggest challenges for nuclear power, and you will look at how Canada plans to manage it in Nuclear and Geothermal Technology and Society.
Accidents and spills. When radioactive material is released, short-half-life isotopes such as iodine-131 are the main hazard in the first weeks, while longer-lived isotopes can contaminate land for decades.
Just for funA banana is very slightly radioactive, thanks to the naturally occurring potassium-40 in it. Potassium-40's half-life is about 1.25 billion years, so your banana will turn brown, spotty and mushy long, long before its potassium-40 is even a tiny bit closer to halfway done.
Hands-on activityCoin-flip half-life
You need: 100 coins (or 100 small pieces of cereal or paper squares marked with an X on one side), a shoebox with a lid, graph paper or a spreadsheet.
- Each coin is an unstable nucleus. Put all 100 in the box, shake it well, and open it.
- Every coin showing heads has "decayed": remove it and count it. Record the number of undecayed coins left.
- Shake again with the coins that are left. Repeat until fewer than 3 coins remain. Each shake is one unit of time.
- Make a table and graph: number of coins remaining (vertical) against number of shakes (horizontal). Draw a smooth curve of best fit.
- On the same axes, plot the theoretical values 100, 50, 25, 12.5, 6.25... Read the half-life of your coins from your curve.
- Extension: use 60 dice instead, and remove every die that rolls a 6. Predict whether the half-life will be longer or shorter than for coins, then test it.
What to look for: your coin half-life should be close to 1 shake, but your numbers will not halve exactly; random decay gives scatter, especially when few coins remain. That is why physicists use huge numbers of nuclei. For dice, only 1 in 6 decays each roll, so the half-life is longer: about 3.8 rolls (because (5/6)^3.8 ≈ ½). In your conclusion, say how combining results from several trials would make your answer more reliable.
Your turn
1What fraction of a radioisotope remains after 4 half-lives?
2Technetium-99m has a half-life of 6.0 h. A patient receives a sample with activity 800 MBq. What is the activity after 24 h?
24 ÷ 6.0 = 4 half-lives. 800 → 400 → 200 → 100 → 50 MBq.
3A 64 g sample of a radioisotope has 4 g left after 20 days. Find its half-life.
64 → 32 → 16 → 8 → 4 is 4 half-lives in 20 days, so T = 5 days.
4A bone fragment has 12.5% of its original carbon-14. How old is it? (T = 5730 years)
12.5% = ⅛ = (½)³: 3 half-lives. Age = 3 × 5730 = 17 190 years.
5Why can't you predict when one particular nucleus will decay?
Decay is random: each nucleus has only a certain probability of decaying in a given time, and nothing outside the nucleus controls it.
6Why are radioisotopes for medical imaging chosen to have short half-lives?
A short half-life means the isotope's activity, and the patient's dose, drops quickly after the images are taken.
7Use N = N₀(½)^(t/T) to find what percentage of tritium (T = 12.3 years) remains after 20.0 years.
t/T = 20.0 ÷ 12.3 = 1.626. (½)^1.626 ≈ 0.324, so about 32% remains.
More practice: warm-up
The time for half of the radioactive nuclei in a sample to decay.
2What is the unit of activity?
The becquerel (Bq): one decay per second.
3100 g of a radioisotope has a half-life of 2 years. How much is left after 2 years?
4How much of that 100 g is left after 6 years?
3 half-lives: 100 → 50 → 25 → 12.5 g.
5Does heating a radioactive sample change its half-life?
No. Half-life is not affected by temperature, pressure or chemical reactions.
More practice: on your own
1A sample of iodine-131 (T = 8.0 days) has an activity of 3.2 × 10⁹ Bq. How long until its activity is 2.0 × 10⁸ Bq?
3.2 × 10⁹ → 1.6 × 10⁹ → 8.0 × 10⁸ → 4.0 × 10⁸ → 2.0 × 10⁸: 4 half-lives = 32 days.
2Cobalt-60 has a half-life of 5.3 years. A hospital replaces its source when the activity falls to 25% of the original. After how many years?
25% = 2 half-lives = 2 × 5.3 = 10.6 years (about 11 years).
3A wooden tool has 6.25% of the carbon-14 of living wood. Estimate its age.
6.25% = 1/16 = (½)⁴: 4 half-lives. Age = 4 × 5730 = 22 920 years.
4A radioisotope has a half-life of 10 minutes. What percentage remains after 25 minutes?
t/T = 2.5. (½)^2.5 ≈ 0.177, so about 18% remains.
5Explain why carbon dating cannot be used to date a 300-million-year-old fossil.
300 million years is over 50 000 half-lives of carbon-14. Essentially no carbon-14 would remain to measure. (Also, many fossils are mineralized rock, not original carbon.) Longer-lived isotopes in nearby rocks are used instead.
Challenge
1A sample contains 1.0 × 10²⁰ atoms of a radioisotope with a half-life of 3.0 hours. How many atoms have decayed after 12 hours?
12 ÷ 3.0 = 4 half-lives. Remaining = 1.0 × 10²⁰ × 1/16 = 6.25 × 10¹⁸. Decayed = 1.0 × 10²⁰ − 6.25 × 10¹⁸ ≈ 9.4 × 10¹⁹ atoms (15/16 of them).
2Two radioisotopes start with equal numbers of nuclei. A has T = 2 days and B has T = 6 days. After 12 days, what is the ratio of A nuclei to B nuclei remaining?
A: 12 ÷ 2 = 6 half-lives, fraction 1/64. B: 12 ÷ 6 = 2 half-lives, fraction 1/4. Ratio A : B = (1/64) ÷ (1/4) = 1 : 16.
3Used CANDU fuel contains plutonium-239 (T ≈ 24 000 years). How long until only about 1/1000 of it remains? Explain why this matters for waste storage.
1/1000 ≈ (½)¹⁰ (since 2¹⁰ = 1024). 10 half-lives ≈ 10 × 24 000 = about 240 000 years. The waste must be kept isolated from people and groundwater for hundreds of thousands of years, far longer than any human building or institution has lasted. That is why Canada plans to store used fuel deep underground in stable rock.
Check your understandingQuiz
1. What is the half-life of a radioisotope?
2. A 40 g sample has a half-life of 3 days. How much remains after 9 days?
3. A sample's activity falls from 600 Bq to 150 Bq in 8 hours. What is the half-life?
4. Charcoal has 50% of the carbon-14 of living wood. Its age is about:
5. Which change would alter the half-life of a radioisotope?
6. Why do medical imaging isotopes such as technetium-99m have short half-lives?
For parents and teachersBig idea: expectation D3.11 asks students to explain half-life and describe its applications and consequences. Decay is random for one nucleus but predictable for many; each half-life the amount halves.
How to help: Do the coin-flip activity together; it takes about 20 minutes and makes half-life concrete. Then ask: "If you start with 1000 and the half-life is 5 minutes, how many after 20 minutes?"
Common difficulties:
- Thinking that after two half-lives everything is gone (it is one-quarter left, not zero).
- Subtracting half the original amount each time instead of halving what is left.
- Mixing up "amount remaining" and "amount decayed" (Challenge 1).
- Calculator errors with non-whole exponents: enter 0.5 ^ (t ÷ T) with brackets.
Connection: the equation N = N₀(½)^(t/T) is an exponential function, which your teen also studies in MCR3U.